Interactions between planar polyelectrolyte brushes: effects of stiffness and salt

Autor(en)

Aaron Wynveen, Christos Likos

Abstrakt

We perform molecular dynamics simulations and develop a theoretical approach based on the two-dimensional cylindrical cell model to investigate the salt-dependent interactions between two sparsely-grafted, rigid polyelectrolyte brushes. Extending our previous study, (A. Wynveen and C.N. Likos, Phys. Rev. E: Stat., Nonlinear, Soft Matter Phys., 2009, 80, 010801), we find that the repulsive force between the brushes arises in equal parts from the compression of osmotically-active counterions trapped within the brushes, and from the necessary distortion of the rigid polyelectrolytes as the brushes approach each other. This latter, bending-force contribution also depends on the ionic environment within the brush as ionic screening reduces the effective persistence length of the polyelectrolyte chains. Our investigations yield results that are consistent with those of experimental studies of the salt-dependent forces between DNA-grafted colloids.

Organisation(en)

Computergestützte Physik und Physik der Weichen Materie

Externe Organisation(en)

Heinrich-Heine-Universität Düsseldorf

Journal

Soft Matter

Band

6

Seiten

163-171

Anzahl der Seiten

9

ISSN

1744-683X

DOI

https://doi.org/10.1039/B919808C

Publikationsdatum

2010

Peer-reviewed

Ja

ÖFOS 2012

1030 Physik, Astronomie

Link zum Portal

https://ucrisportal.univie.ac.at/de/publications/c5913592-3ce9-46a8-9c53-abee390ac52f