High density of genuine growth twins in electrodeposited aluminum

Autor(en)

Lidija D. Rafailović, Christoph Gammer, Christian Ebner, Christian Rentenberger, Aleksandar Z. Jovanović, Igor A. Pašti, Natalia V. Skorodumova, H. Peter Karnthaler

Abstrakt

We demonstrate electrodeposition as a synthesis method for fabrication of Al coatings, up to 10 μm thick, containing a high density of genuine growth twins. This has not been expected since the twin boundary energy of pure Al is very high. TEM methods were used to analyze deposited Al and its nanoscaled twins. DFT methods confirmed that the influence of the substrate is limited to the layers close to the interface. Our findings are different from those achieved by sputtering of Al coatings restricted to a thickness less than 100 nm with twins dominated by epitaxial effects. We propose that in the case of electrodeposition, a high density of twins arises because of fast nucleation and is additionally promoted by a monolayer of adsorbed hydrogen originating from water impurities. Therefore, electrodeposition is a viable approach for tailoring the structure and properties of thicker, deposited Al coatings reinforced by twins.

Organisation(en)

Physik Nanostrukturierter Materialien

Externe Organisation(en)

Kompetenzzentrum für elektrochemische Oberflächentechnologie GmbH , Österreichische Akademie der Wissenschaften (ÖAW), University of Belgrade, KTH - Royal Institute of Technology, Uppsala University

Journal

Science Advances

Band

5

Anzahl der Seiten

7

ISSN

2375-2548

DOI

https://doi.org/10.1126/sciadv.aax3894

Publikationsdatum

10-2019

Peer-reviewed

Ja

ÖFOS 2012

103042 Elektronenmikroskopie, 103018 Materialphysik

Schlagwörter

Link zum Portal

https://ucrisportal.univie.ac.at/de/publications/a22d909a-5081-4c20-812a-1514a0a8f0c3