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Ultrasoft Colloid-Polymer Mixtures: Structure and Phase Diagram

Autor(en)
Barbara Lonetti, Manuel Camargo, Jörg Stellbrink, Christos Likos, Emanuela Zaccarelli, Lutz Willner, Peter Lindner, Dieter Richter
Abstrakt

Binary mixtures of ultrasoft colloids and linear polymer chains were investigated by small-angle neutron scattering and liquid state theory. We show that experimental data can be described by employing recently developed effective interactions between the colloid and the polymer chains, in which both components are modeled as point particles in a coarse-grained approach, in which the monomers have been traced out. Quantitative, parameter-free agreement between experiment and theory for the pair correlations, the phase behavior and the concentration dependence of the interaction length is achieved.

Organisation(en)
Computergestützte Physik und Physik der Weichen Materie
Externe Organisation(en)
Forschungszentrum Jülich, Heinrich-Heine-Universität Düsseldorf, Università degli Studi di Roma La Sapienza, Institut Laue-Langevin (ILL)
Journal
Physical Review Letters
Band
106
Anzahl der Seiten
4
ISSN
0031-9007
DOI
https://doi.org/10.1103/PhysRevLett.106.228301
Publikationsdatum
2011
Peer-reviewed
Ja
ÖFOS 2012
103023 Polymerphysik, 103036 Theoretische Physik, 103015 Kondensierte Materie, 103029 Statistische Physik
Link zum Portal
https://ucrisportal.univie.ac.at/de/publications/9150fba3-760c-4b76-bafb-3db55c361a06