Rheology of a Nanopolymer Synthesized through Directional Assembly of DNA Nanochambers, for Magnetic Applications

Autor(en)

Deniz Mostarac, Sofia S. Kantorovich

Abstrakt

We present a numerical study of the effects of monomer shape and magnetic nature of colloids on the behavior of a single magnetic filament subjected to the simultaneous action of shear flow and a stationary external magnetic field perpendicular to the flow. We find that based on the magnetic nature of monomers, magnetic filaments exhibit a completely different phenomenology. Applying an external magnetic field strongly inhibits tumbling only for filaments with ferromagnetic monomers. Filament orientation with respect to the flow direction is in this case independent of monomer shape. In contrast, reorientational dynamics in filaments with superparamagnetic monomers are not inhibited by applied magnetic fields, but enhanced. We find that the filaments with spherical, superparamagnetic monomers, depending on the flow and external magnetic field strength, assume semipersistent, collapsed, coiled conformations, and their characteristic time of tumbling is a function of field strength. However, external magnetic fields do not affect the characteristic time of tumbling for filaments with cubic, superparamagnetic monomers, but increase how often tumbling occurs.

Organisation(en)

Computergestützte Physik und Physik der Weichen Materie, Forschungsplattform MMM Mathematics-Magnetism-Materials

Journal

Macromolecules

Band

55

Seiten

6462–6473

Anzahl der Seiten

12

ISSN

0024-9297

DOI

https://doi.org/10.1021/acs.macromol.2c00738

Publikationsdatum

07-2022

Peer-reviewed

Ja

ÖFOS 2012

103043 Computational Physics, 103023 Polymerphysik, 103017 Magnetismus

Schlagwörter

ASJC Scopus Sachgebiete

Materials Chemistry, Polymers and Plastics, Inorganic Chemistry, Organic Chemistry

Link zum Portal

https://ucrisportal.univie.ac.at/de/publications/801a092f-5679-40fa-8f96-2274624b2b34