On the Half-Heusler compounds Nb1-x{Ti,Zr,Hf}(x)FeSb: Phase relations, thermoelectric properties at low and high temperature, and mechanical properties

Autor(en)

A. Tavassoli, F. Failamani, A. Grytsiv, G. Rogl, P. Heinrich, H. Mueller, E. Bauer, M. Zehetbauer, P. Rogl

Abstrakt

A re-investigation of phase equilibria, crystal structure and homogeneity region of the Half-Heusler (HH) phase in the ternary system Nb-Fe-Sb at 600 °C has solved controversies in the literature confirming the version of Melnyk et al. ([1] J. Phase Equilibria 20 (2) (1999) 113–118). For the first time transport properties of Half-Heusler (HH) compounds NbFeSb and Nb

_0.85M

_0.15FeSb (M = Ti, Zr, Hf) were studied in the full temperature range from 4.2 to 823 K. The semiconducting material NbFeSb has an electronic structure close to a metal-to-insulator transition, which leads to changes of the conductivity type with the composition as well as with increasing temperature. Ti, Zr and Hf doped NbFeSb alloys show metallic behavior and were confirmed to be high ZT p-type thermoelectric materials. Surprisingly, the lattice thermal conductivity for the Zr-doped composition was found to be higher than those of the Ti- and Hf doped materials; this effect can be explained in terms of mass and strain field fluctuations. For the first time we report experimental information on thermal expansion coefficients, specific heat and elastic moduli for these p-type compounds. The mechanical properties show a good compatibility with those previously reported for n-type HH alloys.

Organisation(en)

Institut für Materialchemie, Physik Nanostrukturierter Materialien

Externe Organisation(en)

Technische Universität Wien

Journal

Acta Materialia

Band

135

Seiten

263-276

Anzahl der Seiten

14

ISSN

1359-6454

DOI

https://doi.org/10.1016/j.actamat.2017.06.011

Publikationsdatum

08-2017

Peer-reviewed

Ja

ÖFOS 2012

104011 Materialchemie, 103018 Materialphysik

Schlagwörter

ASJC Scopus Sachgebiete

Electronic, Optical and Magnetic Materials, Ceramics and Composites, Metals and Alloys, Polymers and Plastics

Link zum Portal

https://ucrisportal.univie.ac.at/de/publications/43a14cf1-671c-4411-bca9-c94df64d98b6