Light absorption by coated nano-sized carbonaceous particles

Autor(en)

Martin Gangl, Miroslav Kocifaj, Gorden Videen, Helmuth Horvath

Abstrakt

The optical properties of strongly absorbing soot particles coated by transparent material are investigated experimentally and described by several modeling approaches. Soot is produced by spark discharge and passed through a Sinclair-La Mer generator where non-absorbing carnauba wax is condensed onto it to obtain internal soot-wax mixtures in a controlled way. Measurements of the extinction and volume scattering coefficient show an amplification of absorption by a factor of approximately 1.8. This behavior was described by different approaches of internally mixed materials for the modal diameters of the measured size distributions: concentric-sphere model, effective medium approximations and heterogeneous ellipsoids. The concentric-sphere model describes the absorption increase quantitatively; and hence, it is chosen to be applied to the entire particle population in the size distribution. The growth of the soot particles by condensing wax is described by a simplified growth model to estimate the different contributions of several soot particle diameters to the overall absorption cross-section.

Organisation(en)

Aerosolphysik und Umweltphysik

Externe Organisation(en)

United States Army Research Laboratory

Journal

Atmospheric Environment

Band

42

Seiten

2571-2581

Anzahl der Seiten

11

ISSN

1352-2310

DOI

https://doi.org/10.1016/j.atmosenv.2007.05.030

Publikationsdatum

2008

Peer-reviewed

Ja

ÖFOS 2012

103008 Experimentalphysik, 105904 Umweltforschung

Link zum Portal

https://ucrisportal.univie.ac.at/de/publications/3f78276e-bbd9-425e-9186-f15905ab6a4a