Dynamics of quantum wave packets in complex molecules traced by 2D coherent electronic correlation spectroscopy

Autor(en)

Tomas Mancal, Oliver Bixner, Niklas Christensson, Jürgen Hauer, Franz Milota, Alexandra Nemeth, Jaroslaw Sperling, Harald Kauffmann

Abstrakt

Electronic and nuclear molecular wavepackets are a clear manifestation of the wavelike properties of matter at the very heart of quantum mechanics. In this work we demonstrate how electronic two-dimensional spectroscopy (2D) serves as a highly evolved tool for the simultaneous investigation of both phenomena. In further analysis and theoretical treatments, 2D spectra form an ideal basis for the discussion of electronic decoherence, vibrational relaxation and electron-phonon coupling.

Organisation(en)

Institut für Organische Chemie, Elektronische Materialeigenschaften, Institut für Physikalische Chemie

Externe Organisation(en)

Charles University Prague, Lund University, Ludwig-Maximilians-Universität München, Newport Spectra-Physics Gmbh

Journal

Procedia Chemistry

Band

3

Seiten

105-117

Anzahl der Seiten

13

DOI

https://doi.org/10.1016/j.proche.2011.08.017

Publikationsdatum

2011

Peer-reviewed

Ja

ÖFOS 2012

103015 Kondensierte Materie, 104001 Allgemeine Chemie

Link zum Portal

https://ucrisportal.univie.ac.at/de/publications/0f87fa61-59a7-408d-a2c6-9bee6df85a76